We measured the thermopower S and the Hall coefficients R_H of Bi_{2}Sr_{2-z}La_{z}CuO_{6+\delta} (BSLCO) single crystals in a wide doping range, in an effort to identify the actual hole concentrations per Cu, p, in this system. It is found that the "universal" relation between the room-temperature thermopower and T_c does not hold in the BSLCO system. Instead, comparison of the temperature-dependent R_H data with other cuprate systems is used as a tool to identify the actual p value. To justify this approach, we compare normalized R_H(T) data of BSLCO, La_{2-x}Sr_{x}CuO_{4} (LSCO), YBa_{2}Cu_{3}O_{y}, and Tl_{2}Ba_{2}CuO_{6+\delta}, and demonstrate that the R_H(T) data of the LSCO system can be used as a template for the estimation of p. The resulting phase diagram of p vs T_c for BSLCO suggests that T_c is anomalously suppressed in the underdoped samples, becoming zero at around p ~ 0.10, while the optimum T_c is achieved at p ~ 0.16 as expected.

Yoichi Ando Y. Hanaki S. Ono T. Murayama Kouji Segawa N. Miyamoto Seiki Komiya

The low-energy excitations of the lightly doped cuprates were studied by angle-resolved photoemission spectroscopy. A finite gap was measured over the entire Brillouin zone, including along the d_{x^2 - y^2} nodal line. This effect was observed to be generic to the normal states of numerous cuprates, including hole-doped La_{2-x}Sr_{x}CuO_{4} and Ca_{2-x}Na_{x}CuO_{2}Cl_{2} and electron-doped Nd_{2-x}Ce_{x}CuO_{4}. In all compounds, the gap appears to close with increasing carrier doping. We consider various scenarios to explain our results, including the possible effects of chemical disorder, electronic inhomogeneity, and a competing phase.

K. M. Shen T. Yoshida D. H. Lu F. Ronning N. P. Armitage W. S. Lee X. J. Zhou A. Damascelli D. L. Feng N. J. C. Ingle H. Eisaki Y. Kohsaka H. Takagi T. Kakeshita S. Uchida P. K. Mang M. Greven Y. Onose Y. Taguchi Y. Tokura Seiki Komiya Yoichi Ando M. Azuma M. Takano A. Fujimori Z. -X. Shen

We report resonant inelastic x-ray scattering studies of electronic excitations in a wide variety of cuprate compounds. Specifically, we focus on the charge-transfer type excitation of an electron from a bonding molecular orbital to an antibonding molecular orbital in a copper oxygen plaquette. Both the excitation energy and the amount of dispersion are found to increase significantly as the copper oxygen bond-length is reduced. We also find that the estimated bond-length dependence of the hopping integral t_pd is much stronger than that expected from tight-binding theory.

Young-June Kim J. P. Hill G. D. Gu F. C. Chou S. Wakimoto R. J. Birgeneau Seiki Komiya Yoichi Ando N. Motoyama K. M. Kojima S. Uchida D. Casa T. Gog

We investigate the hole dynamics in two prototypical high temperature superconducting systems: La$_{2-x}$Sr$_{x}$CuO$_{4}$ and YBa$_{2}$Cu$_{3}% $O$_{y}$ using a combination of DC transport and infrared spectroscopy. By exploring the effective spectral weight obtained with optics in conjunction with DC Hall results we find that the transition to the Mott insulating state in these systems is of the "vanishing carrier number" type since we observe no substantial enhancement of the mass as one proceeds to undoped phases. Further, the effective mass remains constant across the entire underdoped regime of the phase diagram. We discuss the implications of these results for the understanding of both transport phenomena and pairing mechanism in high-T$_{c}$ systems.

W. J. Padilla Y. S. Lee M. Dumm G. Blumberg S. Ono Kouji Segawa Seiki Komiya Yoichi Ando D. N. Basov

Spin-glass magnetism confined to individual weakly interacting vortices is detected in two different families of high-transition-temperature (T_c) superconductors, but only in samples on the low-doping side of the low-temperature normal state metal-to-insulator crossover (MIC). Our findings unravel the mystery of the MIC, but more importantly identify the true location of the field-induced quantum phase transition (QPT) in the superconducting state. The non-uniform appearance of magnetism in the vortex state favours a surprisingly exotic phase diagram, in which spatially inhomogeneous competing order is stabilized at the QPT, and an `avoided' quantum critical point (QCP) is realized at zero magnetic field.

J. E. Sonier F. D. Callaghan Y. Ando R. F. Kiefl J. H. Brewer C. V. Kaiser V. Pacradouni S. -A. Sabok-Sayr X. F. Sun S. Komiya W. N. Hardy D. A. Bonn R. Liang

Highly disordered magnetism confined to individual weakly interacting vortices is detected by muon spin rotation in two different families of high-transition-temperature superconductors, but only in samples on the low-doping side of the low-temperature normal state metal-to-insulator crossover (MIC). The results support an extended quantum phase transition (QPT) theory of competing magnetic and superconducting orders that incorporates the coupling between CuO2 planes. Contrary to what has been inferred from previous experiments, the static magnetism that coexists with superconductivity near the field-induced QPT is not ordered. Our findings unravel the mystery of the MIC and establish that the normal state of high-temperature superconductors is ubiquitously governed by a magnetic quantum critical point in the superconducting phase.

J. E. Sonier F. D. Callaghan Y. Ando R. F. Kiefl J. H. Brewer C. V. Kaiser V. Pacradouni S. A. Sabok-Sayr X. F. Sun S. Komiya W. N. Hardy D. A. Bonn R. Liang

We report that in YBa2Cu3Oy and La2-xSrxCuO4 there is a spatially inhomogeneous response to magnetic field for temperatures T extending well above the bulk superconducting transition temperature Tc. An inhomogeneous magnetic response is observed above Tc even in ortho-II YBa2Cu3O6.50, which has highly ordered doping. The degree of the field inhomogeneity above Tc tracks the hole doping dependences of both Tc and the density of the superconducting carriers below Tc, and therefore is apparently coupled to superconductivity.

J. E. Sonier M. Ilton V. Pacradouni C. V. Kaiser S. A. Sabok-Sayr Y. Ando S. Komiya W. N. Hardy D. A. Bonn R. Liang W. A. Atkinson

We report a novel aspect of the competition and coexistence between magnetism and superconductivity in the high-$T_{c}$ cuprate La$_{2-x}$Sr$_{x}$CuO$_{4}$ (La214). With a modest magnetic field applied $H \parallel c$-axis, we monitored the infrared signature of pair tunneling between the CuO$_2$ planes and discovered the complete suppression of interlayer coupling in a series of underdoped La214 single crystals. We find that the in-plane superconducting properties remain intact, in spite of enhanced magnetism in the planes.

A. A. Schafgans A. D. LaForge S. V. Dordevic M. M. Qazilbash W. J. Padilla K. S. Burch Z. Q. Li Seiki Komiya Yoichi Ando D. N. Basov

We present Raman scattering experiments in ${\rm La_{2-x}Sr_xCuO_4}$ single crystals at various doping levels x and compare the results with theoretical predictions obtained assuming an interaction mediated by spin and charge fluctuations. The light-scattering selection rules allow us to disentangle their respective contributions. We find that the glue spectral function is spin-dominated at low doping while the contribution of charge fluctuations becomes dominant around optimal doping. This indicates that the fluctuations of a nearly ordered state with coexisting spin and charge order support the superconducting pairing.

S. Caprara C. Di Castro B. Muschler R. Hackl M. Lambacher A. Erb S. Komiya Y. Ando M. Grilli

The superconductivity of cuprates, which has been a mystery ever since its discovery decades ago, is created through doping electrons or holes into a Mott insulator. There, however, exists an inherent electron-hole asymmetry in cuprates. The layered crystal structures of cuprates enable collective charge excitations fundamentally different from those of three-dimensional metals, i.e., acoustic plasmons. Acoustic plasmons have been recently observed in electron-doped cuprates by resonant inelastic X-ray scattering (RIXS); in contrast, there is no evidence for acoustic plasmons in hole-doped cuprates, despite extensive measurements. This contrast led us to investigate whether the doped holes in cuprates La$_{2-x}$Sr$_x$CuO$_4$ are conducting carriers or are too incoherent to induce collective charge excitation. Here we present momentum-resolved RIXS measurements and calculations of collective charge response via the loss function to reconcile the aforementioned issues. Our results provide unprecedented spectroscopic evidence for the acoustic plasmons and long sought conducting p holes in hole-doped cuprates.

A. Singh H. Y. Huang Christopher Lane J. H. Li J. Okamoto S. Komiya Robert S. Markiewicz Arun Bansil A. Fujimori C. T. Chen D. J. Huang